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            OilfieldTechnology
          
        
        
          
            February
          
        
        
          2014
        
        
          channels intherock,whichcan increasetheextractionratesandultimate
        
        
          recoveryofhydrocarbons.
        
        
          Themorecommonfracturingfluidsusedtodayaregelledor
        
        
          water‑based,andCO
        
        
          2
        
        
          andN
        
        
          2
        
        
          havebuiltareputationofbeingfluidsthatcan
        
        
          reliablybeharnessedforthesuccessfulhydraulicfracturingandstimulation
        
        
          ofwells.Recentstudies indicatethat, fromaneconomicperspective,
        
        
          hydraulicfracturingwithsolutionsenergisedbyCO
        
        
          2
        
        
          orN
        
        
          2
        
        
          canachieve
        
        
          significantlymorehydrocarbonrecoverythannon‑energisedapproaches.
        
        
          Onesuchstudyfoundthatuseofenergisedfluids improvedwell
        
        
          performancebyupto2.1times,comparedwithnon‑energisedsolutions.
        
        
          Theultimategoalofwellstimulation istoachievemaximum
        
        
          productivityatthe lowestunitcost,butachievingeconomicallydesirable
        
        
          fracturepenetrationandconductivitycanbeparticularlychallenging in
        
        
          unconventionalreservoirs.Fracturingwithfluidsthatarenotenergisedcan
        
        
          leave liquidstrapped in low‑permeability,tight,depletedor
        
        
          water‑sensitiveformations.Thisfluidremaining intheformation lowers
        
        
          thefractureconductivity,reducingor impedingtheflowofoilandgas.Very
        
        
          often inwater‑basedhydraulicfracturingfluids,themajorityofthewater
        
        
          isneverrecoveredfromunconventionalreservoirsandthewaterthat is
        
        
          recovered iscontaminated.
        
        
          Proppantcanbe improperlydeposited,resulting inblockingor
        
        
          impedingflowandherefoamedenergisedfracturingfluidsareproviding
        
        
          superiorproppanttransportproperties.Gelledfracturingfluidsmustbe
        
        
          flushedfromtheformationtocleanoutasmuchresidueaspossiblefrom
        
        
          theproppantpack.
        
        
          EnergisingthefracturingfluidwithCO
        
        
          2
        
        
          orN
        
        
          2
        
        
          also improvesthetotal
        
        
          flowbackvolumeandrate,minimisesfluidretentionandreducesthe
        
        
          requiredwatervolume,whichhassignificanteconomic implications.CO
        
        
          2
        
        
          actuallyvaporisesatreservoirconditions, leavinga liquid‑freeproppant
        
        
          pack.
        
        
          Avoidingdamage,definedas ‘any inducedreservoirchangethat inhibits
        
        
          orrestrictshydrocarbonflowduringwellstimulation’, iscritical.There is
        
        
          evidencethattheuseofthese industrialgasesalsoreducesthedamage
        
        
          causedbyproppant, fracturesthataretoofarapartandresiduefrom
        
        
          polymersandgels.
        
        
          Theflexibilityofenergisedsolutionsallowsforthehydraulicfracturing
        
        
          fluidtobemixedaccordingtothetechnologicalneedsofunconventional
        
        
          reservoirs.Theyprovidemorerapidandcompletetreatmentfluidrecovery,
        
        
          helptocleanwithouttheneedforswabbingandreduceformationdamage
        
        
          byminimisingtheamountofaqueousfluids introducedtotheformation.
        
        
          Energisedsolutionsalsooffertheabilitytohavesuperior
        
        
          proppant‑transportpropertiesand, inthecaseofunderpressuredor
        
        
          depletedzones,provideenhancedenergyforhydrocarbonrecovery.
        
        
          Flexibility insolutionviscosityallowsforamoreuniformdeposition
        
        
          ofproppants, improvingconductivityoftheproppedareatoenhancethe
        
        
          
            Figure4.
          
        
        
          When injected intowellsenergisedLINandCO
        
        
          2
        
        
          gassolutions
        
        
          areabletoenhancehydrocarbonproductionratesandyields.
        
        
          flowofhydrocarbons. Inunconventionalreservoirs,energisedsolutions
        
        
          providethenecessary lifttomovehydrocarbons in lowpressurezonesor
        
        
          areaswithstrongcapillaryforces.Thesolubilityandmiscibilityproperties
        
        
          ofCO
        
        
          2
        
        
          providegreateropportunitytoenergisetheflowofmoreviscous
        
        
          hydrocarbons.
        
        
          
            Extractionandprocessing
          
        
        
          Nitrogen (N
        
        
          2
        
        
          )andcarbondioxide (CO
        
        
          2
        
        
          )asbulkgasesareused in
        
        
          hugequantities fortheextractionandexplorationofnaturalgaswith
        
        
          inducedhydraulic fracturing.Thetraditionalprocess forpropagating
        
        
          hydrocarbonstrapped inunderground fractureshadrequiredhigh
        
        
          volumesofwater,mixedwith foamingagentsand frictionreducersand
        
        
          injectedathighpressure intothe fractures,crackingopentheshaleand
        
        
          creating fissuresallowinggasoroilcontainedwithinthemto flow freely.
        
        
          Alternativetechniques,whichcanhelpmitigatewater‑related
        
        
          issues in fracturing, includeemployingCO
        
        
          2
        
        
          mixedwithalcoholor liquid
        
        
          nitrogen (LIN) inaprocessknownas ‘dry fracturing’.TheCO
        
        
          2
        
        
          /alcohol
        
        
          mix isalso injectedathighpressureundergroundtoopenup fractures,
        
        
          withtheCO
        
        
          2
        
        
          expandingas itvaporises,allowingnaturalgasto flowout
        
        
          throughthecrackstobecollectedandprocessed.
        
        
          Liquidnitrogen isusedfor ‘dryfracking’–afracturingprocessthat
        
        
          haseliminatedmanyoftheproblemsassociatedwithhydrofracturing
        
        
          andcouldprovetobemoreacceptabletopeopleconcernedabout
        
        
          theenvironment. Itusesveryfew,ornochemicals,andafterfracturing
        
        
          thenitrogen isreleased intotheatmosphere,whichalreadycomprises
        
        
          78%nitrogen.Nitrogenhasbeenshowntoyieldhighereconomicvalue
        
        
          incomparisontoconventionalchemical fracturing; it isbeingused
        
        
          extensivelyfornaturalgasextraction inareasofhighenvironmental
        
        
          sensitivity.
        
        
          
            Replacingwater
          
        
        
          Asthe industrycontinuesto focusonreducingtheamountofwater
        
        
          required forhydraulic fracturinganddevelopingcompletiondesignsto
        
        
          sustainwellproduction,greateremphasis isbeingplacedontheuseof
        
        
          cryogenicgasesandassociated fieldsupportservicestoachievethese
        
        
          goals.
        
        
          LindeGasproducesN
        
        
          2
        
        
          andCO
        
        
          2
        
        
          in liquid format facilitiescloseto
        
        
          hydraulic fracturingsitesanddeliversthesegasesontosite inroad
        
        
          tankers.Withthousandsof tonnesof this liquidgasrequiredatany
        
        
          onetime,delivery isoftenmadetoan intermediarysitewhere it is
        
        
          stored in largecontainersaveragingacapacityof70t.Thecompany
        
        
          managesthese logisticsandownsthedistributionequipmentrequired
        
        
          toundertaketheconnectionstopumpsandassociatedmixtures.
        
        
          Thisensuresthatthenecessaryexpertise isavailableandprovides
        
        
          compliancewithsafetyregulations.Allwellsitesare inspectedandhave
        
        
          adocumentedriskassessmentperformedbytrainedpersonnel.
        
        
          Lastyear, thecompany introducednitrogenportablestorage
        
        
          vessels (NPSVs) thatenablehydraulic fracturingoperatorsandservice
        
        
          companiestoexpandtheirnitrogenstoragecapabilitieson location.
        
        
          Providing16700gal.ofstoragecapacity,NPSVsaretransportable
        
        
          cryogenicvesselsthatallowhighvolume liquidnitrogentobedelivered
        
        
          directlytoproduction locations,minimisingtheneed forongoing
        
        
          shuttlingofnitrogen fromstagingareastoproduction locations
        
        
          andreducingthecostsanddelaysassociatedwith interruptions
        
        
          from frequentdeliveries.Thisapproachalsominimisesoperational
        
        
          complexitiesnearthewellhead.
        
        
          NPSVsoffernumerousbenefits, includingasmaller footprintand
        
        
          significantlyreduced labourandequipmentcostsassociatedwiththe
        
        
          ongoingshuttlingofnitrogen fromthestagingareatothewellhead.
        
        
          Unliketheconventional largercontainers,NPSVsdonotrequire
        
        
          DepartmentofTransportationpermitsandallow formanoeuvringonthe
        
        
          mostchallengingoff‑roadterrains.